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    Acrylic Primer#1602 LANG丙烯酸底漆
  • 产品名称:Acrylic Primer#1602 LANG丙烯酸底漆
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    SAFETY DATA SHEET

    Issue Date

    26-Sept-2014

    Revision Date

    14-July-2015

    Version 3

     

     

     

     

     

     

    1.  IDENTIFICATION

     

    Product Identifier

     

     

     

     

    Product Name

    ACRYLIC PRIMER / JET SEAL

     

     

    Other means of identification

     

     

     

    SDS#

    041

     

     

     

    UN/ID No

    UN1247

     

     

     

    Product Code

    1602, 1607, 1608 / 4102, 4106, 4107, 4108

     

     

    Recommended use of the chemical and restrictions on use

     

     

    Recommended Use

    Acrylic Primer - Acrylic bonding agent / Jet Seal - Acrylic sealing agent

    Acrylic Primer#1602 LANG丙烯酸底漆 

     

     

     

    2. HAZARDS IDENTIFICATION

    Classification

     

     

     

     

     

     

     

     

     

     

     

    Flammable liquids

     

     

     

    Category 2

     

    Skin Corrosion / Irritation

     

     

    Category 2

     

    Skin Sensitization

     

     

     

    Category 1

     

    Specific Target Organ Toxicity - Single Exposure

     

    Category 3

     

    (Respiratory)

     

     

     

     

     

    Signal word

    Danger

     

     

     

    Hazard statements

    H225

    Highly flammable liquid and vapor.

     

    H315

    Causes skin irritation.

    Acrylic Primer#1602 LANG丙烯酸底漆 

    H317 May cause an allergic skin reaction.

     

    H335 May cause respiratory irritation.

    Acrylic Primer / Jet Seal 041 v. 3 Page 1 of 8

    Appearance Clear Physical state Liquid Odor Acrid

     

    Precautionary Statements – Prevention

     

    P210 Keep away from heat/sparks/open flames/ hot surfaces. No smoking.

     

    P233 Keep container tightly closed.

     

    P240 Ground/bond container and receiving equipment.

     

    P241 Use explosion-proof electrical/ventilating/lighting/equipment.

     

    P242 Use only non-sparking tools.

     

    P243 Take precautionary measures against static discharge.

     

    P261 Avoid breathing dust/fume/gas/mist/vapors/spray.

     

    P264 Wash hands thoroughly after handling.

     

    P271 Use only outdoors or in a well-ventilated area.

     

    P272 Contaminated work clothing should not be allowed out of the workplace.

     

    P280 Wear protective gloves/protective clothing/eye protection/face protection.

     

    Precautionary Statements – Response

     

    P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediay all contaminated clothing. Rinse skin with water/shower.

     

    P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P312 Call a POISON CENTER or doctor/physician if you feel unwell.

     

    P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P362 Take off contaminated clothing and wash before use.

     

    P370+P378 In case of fire: Use CO2, for extinction.

     

    Precautionary Statements – Storage

     

    P403+P233 Store in a well-ventilated place. Keep container tightly closed.

    P403+P235 Store in a well-ventilated place. Keep cool.

     

    Precautionary Statements – Disposal

     

    P501 Dispose of contents/container in accordance with local regulation.

     

    Hazardous Component(s) Contains methyl methacrylate

    for labeling

     

    Hazards not otherwise classified (HNOC) Not applicable

     

    Other Information Harmful to aquatic life

    3. COMPOSITION / INFORMATION ON INGREDIENTS

     

    Chemical Name

    CAS No

    Weight - %

    Trade Secret

    Methyl Methacrylate

    80-62-6

    <100

    *

    *Specific chemical weight has been

    withheld as a trade secret.

     

     

     

     

    4. FIRST AID MEASURES

    First aid measures

     

    Acrylic Primer / Jet Seal 041  v. 3

    Page 2 of 8


     

     

    ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Use personal protective equipment as required. Ensure adequate ventilation. Remove any contaminated clothing and wash thoroughly before reuse.

    Inhalation

    Remove victim to fresh air and keep at rest in a position comfortable for breathing. Keep patient warm and at

     

    rest. Call a physician or poison control center immediay.

    Eye contact

    Immediay flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing

     

    for at least 15 minutes. Call a physician immediay.

    Ingestion

    Do NOT induce vomiting. Drink plenty of water or milk immediay. Never give anything by mouth to an

     

    unconscious person. Provide an estimate of the time at which the material was ingested and the amount of

     

    the substance that was swallowed. Call a physician or poison control center immediay.

    Skin Contact

    Wash off immediay with plenty of soap and water. Take off contaminated clothing. Wash contaminated

     

    clothing before reuse. If skin irritation or rash occurs, get medical advice/attention.

    Most important symptoms and effects, both acute and delayed

    Symptoms

    May cause skin and eye irritation to the mucous membranes and upper respiratory tract.

    Indication of any immediate medical attention and special treatment needed

    Note to physicians

    Treat symptoms conventionally, after thorough decontamination.

     

     

     

    5. FIRE-FIGHTING MEASURES

     

    Extinguishing Media

     

    Suitable: Chemical foam, carbon dioxide (CO2), dry chemical

     

    Unsuitable: Water spray

     

    Specific hazards arising from the chemical

     

    For bulk size >1L – High temperatures, inhibitor depletion, accidental impurities, or exposure to radiation or oxidizers may cause spontaneous polymerizing reaction generating heat/pressure. Closed containers may rupture or explode during a runaway polymerization. Use a water spray or fog to reduce or direct vapors. Extremely flammable. Vapors are heavier than air and may spread along the floors. Vapors may travel to source of ignition and flash back. Heat/impurities may cause pressure to build and/or rupture closed containers, spreading fire, increasing risk or burns/injuries.

     

    Hazardous Combustion Products: Carbon oxides

     

    Sensitivity to Mechanical Impact: No

     

    Sensitivity to Static Discharge: Yes

     

    Protective equipment and precautions for firefighters

     

    As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Fight fire from a safe location.

    6. ACCIDENTAL RELEASE MEASURES

     

    Personal precautions, protective equipment and emergency procedures

     

    Personal precautions

     

     

     

    Environmental precautions Prevent product from entering drains. Spillages or uncontrolled discharges into watercourses must

     

    be alerted to the appropriate regulatory body.

     

    Methods and material for containment and clean-up

     

    Method for containment Absorb with earth, sand or other non-combustible material and transfer to containers for later

     

    disposal. DO NOT use combustible materials such as sawdust.

     

    Method for clean-up Use only non-sparking tools. Wash all affected areas with plenty of warm water and soap.

     

    Acrylic Primer / Jet Seal 041 v. 3 Page 3 of 8


     

    If anticipated that prolonged and repeated skin contact will occur during use of this product, wear gloves for routine industrial use. If necessary, refer to US OSHA 29CFR SS1910.138 or the appropriate standards of Canada or the EC member states. Wear suitable protective clothing.

     

    Depending on the use of this product, safety glasses or goggles may be worn. If necessary, refer to US OSHA 29CFR SS1910.133, Canadian standards or the European Standard EN 166. Ensure that an eyewash station, sink or washbasin is available in case of exposure to eyes.

     

    Keep in original container.

    Strong oxidizing agents, strong reducing agents, free-radical generators, inert gases, oxygen scavengers

    Material has strong solvent properties and can soften paint and rubber.

    8. EXPOSURE CONTROLS / PERSONAL PROTECTION

    Consideration should be given to the work procedures involved and the potential extent of exposure as they may determine whether a higher level of protection is required. The following information is given as general guidance.

     

    Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat, sparks, flame and other sources of ignition (i.e. pilot lights, electric motors and static electricity). Protect from direct sunlight. Keep container closed to prevent water absorption and contamination. Methacrylate stored in bulk must be kept in contact with air (oxygen). Keep at a temperature not exceeding 25°C.

    7. HANDLING AND STORAGE

     

    Precautions for safe handling

     

    Advice on safe handling Observe precautions found on the label. Keep containers closed when not in use. All equipment used when handling the product must be grounded. Use non-sparking hand tools and explosion-proof electrical equipment. Avoid contact with skin and eyes. Avoid breathing vapors or mists. Use only in well-ventilated areas. Vapors are heavier than air and may travel along the floor and in the bottom of containers. Take precautionary measures against static discharges. Wash thoroughly after handling. Use personal protection recommended in Section 8. Contaminated work clothing should not be allowed out of the workplace. Keep away from heat, sparks, open flames, and hot surfaces. NO SMOKING.

     

    Conditions for safe storage, including any incompatibilities

     

    Storage Conditions

    Packaging materials

    Incompatible materials

    Exposure guidelines

     

    Chemical Name

    ACGIH TLV

    OSHA PEL

    NIOSH IDLH

    Methyl Methacrylate

    S 100 ppm

    TWA:100 ppm

    IDLH: 1,000 ppm

    80-62-6

    TWA: 50 ppm

    TWA: 410 mg/m3

    TWA: 100 ppm

     

     

     

    TWA: 410 mg/m3

    Appropriate engineering controls

    Engineering controls Apply technical measures to comply with the occupational exposure limits. Eyewash stations

    Individual protection measures, such as personal protective equipment

    Eye / face protection

    Skin and body protection

    Acrylic Primer / Jet Seal 041 v. 3 Page 4 of 8


     

    Respiratory protection

    Wear suitable respiratory equipment if exposure to levels above the occupational exposure limit is

     

     

    likely. A suitable mask with filter type A may be appropriate. In the event of formation of particularly

     

     

    high levels of vapor, a self-contained breathing apparatus may be appropriate.

    General hygiene considerations

    Handle in accordance with good industrial hygiene and safety practice.

     

     

     

     

     

     

    9. PHYSICAL AND CHEMICAL PROPERTIES

     

     

     

     

    Information on basic physical and chemical properties

     

     

    Physical state

     

    Liquid

    Odor

    Acrid

    Appearance

     

    Liquid

    Odor threshold

    Not determined

    Color

     

    Clear

     

     

    Property

     

    Values

    Remarks / Method

     

    pH

     

    Not determined

     

     

    Melting point /

    freezing point

    Not determined

     

     

    Boiling point / boiling range

    101°C / 214° F

     

     

    Flash point

     

    11.5°C / 52.7°F

     

     

    Evaporation rate

    3.1

    Butyl acetate = 1

     

    Flammability (solid, gas)

    n/a (liquid)

     

     

    Flammability limits in air

     

     

     

    Upper flammability limit

    12.5%

     

     

    Lower flammability limit

    2.12%

     

     

    Vapor pressure

     

    28mm Hg

    @ 20°C

     

    Vapor density

     

    3.5

    @15.5°C (Air = 1)

     

    Specific gravity

     

    0.891

    Water = 1

     

    Water solubility

     

    1.6 wt%

     

     

    Solubility in other solvents

    Not determined

     

     

    Partition coefficient

    Not determined

     

     

    Autoignition temperature

    421°C / 790°F

     

     

    Decomposition temperature

    Not determined

     

     

    Kinematic viscosity

    Not determined

     

     

    Dynamic viscosity

    Not determined

     

     

    Explosive properties

    Not determined

     

     

    Oxidizing properties

    Not determined

     

     

    Other information

     

     

     

    Density

     

    0.891 g/mL

     

     

     

     

     

     

     

     

    10. STABILITY AND REACTIVITY

     

     

     

     

     

    Reactivity

    Not reactive under normal conditions

     

     

     

    Chemical stability Unstable / reactive upon depletion of inhibitor

     

    Possibility of hazardous reactions

     

    None under normal processing

     

    Hazardous polymerization Hazardous polymerization may occur. Monomer vapors are inhibited and may form polymers in vent or flame arresters, resulting in blockage of vents.

     

    Conditions to avoid

     

    Temperatures above 25°C (77°F), localized heat sources (e.g. drum or band heaters), oxidizing conditions, freezing conditions, direct sunlight, ultraviolet radiation, inert gas blanketing

     

    Incompatible materials

     

    Strong oxidizing agents, strong reducing agents, free-radical generators, inert gases, oxygen scavengers

     

    Material has strong solvent properties and can soften paint and rubber.

     

    Hazardous decomposition products Carbon oxides

     

    Acrylic Primer / Jet Seal 041 v. 3 Page 5 of 8


     

     

    May cause allergic skin reaction.

    Not classifiable as a human carcinogen

     

     

    11. TOXICOLOGICAL INFORMATION

     

     

     

     

     

     

    Information on likely routes of exposures

     

     

     

    Product information

     

     

     

     

     

    Inhalation

    Avoid breathing vapors or mists.

     

     

     

    Eye contact

    Causes severe eye irritation.

     

     

     

    Skin contact

    Causes skin irritation.

     

     

     

    Ingestion

    Not expected to be toxic following ingestion of amount recommended for use.

     

    Component information

     

     

     

     

     

     

     

     

     

     

     

    Chemical Name

     

    ORAL LD50

    DERMAL LD50

     

    INHALATION LC50

    Methyl Methacrylate

     

    7872 mg/kg (rat)

    >5 g/kg (rabbit)

     

    400 ppm (rat) 1 h

    80-62-6

     

     

     

     

    4632 ppm (rat) 4 h

     

     

     

     

     

    Information on physical, chemical and toxicological effects

     

     

     

    Symptoms

    May cause skin and eye irritation. May cause irritation to the mucous membranes and upper respiratory tract.

     

    Delayed and immediate effects as well as chronic effects from short and long-term exposure

     

    Sensitization

     

    Carcinogenicity

     

    Chemical Name

    ACGIH

    IARC

    NTP

    OSHA

    Methyl Methacrylate

    -

    Group 3

    -

    -

    80-62-6

     

     

     

     

     

     

     

     

     

    IARC (International Agency

    for Research on Cancer)

    Group 3 IARC components are “not classifiable as human carcinogens”

     

    STOT – single exposure May cause respiratory irritation. May cause drowsiness or dizziness.

     

    Numerical measures of toxicity  Product Not determined

     

    The following values are calculated based on chapter 3.1 of the GHS document.

     

    ATEmix (oral)

    7874

    mg/kg

    ATEmix (dermal)

    5005

    mg/kg

    ATEmix (inhalation-gas)

    400

    mg/kg

    12. ECOLOGICAL INFORMATION

     

    Ecotoxicity Harmful to aquatic life.

     

    Chemical Name

    Algae / aquatic plants

    Fish

    Toxicity to

    Crustacea

     

     

     

    microorganisms

     

    Methyl

    170: 96 h

    125.5-190.7: 96 h Pimephales

    -

    69: 48 h Daphnia magna

    Methacrylate

    Psuedokirchneriella

    promelas mg/L LC50 static;

     

    mg/L EC50

    80-62-6

    subcapitata mg/L EC50

    153.9-341.8: 96 h Lepomis macrochirus mg/L

     

     

     

     

    LC50 static;

     

     

     

     

    170-206: 96 h Lepomis macrochirus mg/L

     

     

     

     

    LC50 flow -through;

     

     

     

     

    243-275: 96 h Pimephales promelas mg/L

     

     

     

     

    LC50 flow-through;

     

     

     

     

    326.4-426.9 96 h Poecilia reticulata mg/L

     

     

     

     

    LC50 static;

     

     

     

     

    >79: 96 h Oncorhynchus mykiss mg/L LC50

     

     

     

     

    flow-through;

     

     

     

     

    >79: 96 h Oncorhynchus mykiss mg/L LC50

     

     

     

     

    static

     

     

    Acrylic Primer / Jet Seal 041  v. 3

     

     

    Page 6 of 8


     

     

     

    Persistence and degradability Not readily biodegradable

     

     

     

     

     

     

     

    Bioaccumulation

    Not determined

     

     

     

     

     

     

     

    Mobility

    Potential for mobility in soil is very high.

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

    Chemical Name

     

     

     

    Partition coefficient

     

     

     

     

     

     

    Methyl Methacrylate

     

     

     

    0.7

     

     

     

     

     

     

     

    80-62-6

     

     

     

     

     

     

     

     

     

     

     

     

     

    Other adverse effects

    COD = 88% (28 days), DOC removal > 95% (28 days)

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

    13. DISPOSAL CONSIDERATIONS

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

    Waste treatment methods

     

     

     

     

     

     

     

     

     

     

     

     

     

    Disposal of wastes

     

    Follow all local and national government regulations in disposing material or contaminated

     

     

     

     

     

     

    packaging.

     

     

     

     

     

     

     

     

     

     

     

    For U.S. - Dispose of in accordance with federal, state and local regulations. When discarded, it is

     

     

     

     

     

     

    considered a hazardous waste by the EPA under RCRA. The reportable quantity for methyl

     

     

     

     

     

     

    methacrylate is 1000 lb. (40 CFR Part 302). Add excess inhibitor before disposing.

     

     

    Contaminated Packaging

     

    Reuse of empty drums or containers is not recommended. Employees should be advised of the

     

     

     

     

     

     

    potential hazards due to residual material associated with empty containers. Dispose of all empty

     

     

     

     

     

     

    containers properly in accordance with federal, state and local regulations.

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

    Chemical Name

     

    RCRA

     

    RCRA – Basis for Listing

    RCRA – D Series Wastes

     

    RCRA – U Series Wastes

     

     

    Methyl Methacrylate

     

    U162

     

     

    Included in waste stream;

    -

     

     

     

    U162

     

     

    80-62-6

     

     

     

     

     

    F039

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

    Chemical Name

     

     

    California Hazardous Waste Status

     

     

     

     

     

    Methyl Methacrylate

     

     

     

    Toxic Ignitable

     

     

     

     

     

     

     

    80-62-6

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

    14. TRANSPORTATION INFORMATION

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

    DOT

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

    UN / ID No

     

     

     

     

     

    UN1247

     

     

     

     

     

     

     

     

    Proper shipping name

     

     

     

     

     

    Methyl Methacrylate monomer, stabilized

     

     

     

     

    Hazard Class

     

     

     

     

     

    3

     

     

     

     

     

     

     

     

    Packing Group

     

     

     

     

     

    II

     

     

     

     

     

     

     

     

    Reportable Quantity (RQ)

     

     

     

     

     

    1000 lb.

     

     

     

     

     

     

     

    IATA

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

    UN / ID No

     

     

     

     

     

    UN1247

     

     

     

     

     

     

     

     

    Proper shipping name

     

     

     

     

     

    Methyl Methacrylate monomer, stabilized

     

     

     

     

    Hazard Class

     

     

     

     

     

    3

     

     

     

     

     

     

     

     

    Packing Group

     

     

     

     

     

    II

     

     

     

     

     

     

     

    IMDG

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

    UN / ID No

     

     

     

     

     

    UN1247

     

     

     

     

     

     

     

     

    Proper shipping name

     

     

     

     

     

    Methyl Methacrylate monomer, stabilized

     

     

     

     

    Hazard Class

     

     

     

     

     

    3

     

     

     

     

     

     

     

     

    Packing Group

     

     

     

     

     

    II

     

     

     

     

     

    Acrylic Primer / Jet Seal 041 v. 3 Page 7 of 8

     

     

     

     

    15. REGULATORY INFORMATION

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

    International Inventories

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

    TSCA

    Listed

     

    United States Toxic Substances Control Act, Section 8(b) Inventory

     

     

     

    DSL

    Listed

     

    Canadian Domestic Substances List

     

     

     

     

     

     

     

    EINECS

    Listed

     

    European Inventory of Existing Chemical Substances

     

     

     

    EU Regulations

    EC No. 1272/2008 (CLP) Classification, Labeling, Packaging

     

     

     

     

     

     

     

     

    Medical Devices Directive 93/42/EEC - Class I Medical Devices

     

     

     

     

     

     

     

    US Federal Regulations

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

    Chemical Name

     

    CAS

     

     

     

    Weight %

     

    SARA 313 Threshold Values %

     

     

    Methyl Methacrylate

     

    80-62-6

     

     

     

    < 100

     

     

    1.0

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

    SARA 311 / 312 Hazard Categories

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

    Chemical Name

     

     

    CWA – Reportable

     

     

    CWA – Toxic

     

     

    CWA – Priority

     

    CWA – Hazardous

     

     

     

     

     

    Quantities

     

     

    Pollutants

     

     

    Pollutants

     

    Substances

     

    Methyl Methacrylate

     

     

    1,000 lb.

     

     

    -

     

     

    -

     

     

    X

     

    80-62-6

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

    Chemical Name

     

    Hazardous Substances

     

    CERCLA /

     

     

    Reportable Quantity (RQ)

     

     

     

     

     

    RQs

     

    SARA RQ

     

     

    Final

     

     

     

    Methyl Methacrylate

     

    1,000 lb.

     

    -

     

     

     

    1,000 lb. / 454 kg

     

     

     

    80-62-6

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

    US State Right-to-Know Regulations

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

    Chemical Name

     

     

     

    CAS

     

     

    New Jersey

     

    Massachusetts

     

    Pennsylvania

    Methyl Methacrylate

    80-62-6

     

     

     

     

    X

     

    X

     

     

    X

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

     

    16. OTHER INFORMATION

     

    NFPA

    Health Hazards

     

    Flammability

    Instability

     

     

    2

     

    3

    2

     

    HMIS

    Health Hazards

     

    Flammability

    Physical Hazards

     

     

    2

     

    3

    2

     

    Issue Date

    26-Sept-2014

     

     

     

     

    Revision Date

    14-July-2015

     

     

     

     

    Revision Note

    Section 2 – revise classification categories, revise some Hazard Statements and Precautionary Statements,,

     

    add hazardous component for labeling info

     

     

    Information to be updated in due course

    Hazard pictograms listed in this SDS to be added to product label

     

    Disclaimer

     

    The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release. It is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

     

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