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Acrylic Primer#1602 LANG丙烯酸底漆

产品简介:Acrylic Primer#1602 LANG丙烯酸底漆
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We recommend applying a priming liquid to prepare any acrylic surface for repair or buildup.
This product is specifically formulated to ensure uniform bonding,

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更新时间:2023-04-02

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产品介绍

只用于动物实验研究等

 

 

 

 

SAFETY DATA SHEET

Issue Date

26-Sept-2014

Revision Date

14-July-2015

Version 3

 

 

 

 

 

 

1.  IDENTIFICATION

 

Product Identifier

 

 

 

 

Product Name

ACRYLIC PRIMER / JET SEAL

 

 

Other means of identification

 

 

 

SDS#

041

 

 

 

UN/ID No

UN1247

 

 

 

Product Code

1602, 1607, 1608 / 4102, 4106, 4107, 4108

 

 

Recommended use of the chemical and restrictions on use

 

 

Recommended Use

Acrylic Primer - Acrylic bonding agent / Jet Seal - Acrylic sealing agent

Acrylic Primer#1602 LANG丙烯酸底漆 

 

 

 

2. HAZARDS IDENTIFICATION

Classification

 

 

 

 

 

 

 

 

 

 

 

Flammable liquids

 

 

 

Category 2

 

Skin Corrosion / Irritation

 

 

Category 2

 

Skin Sensitization

 

 

 

Category 1

 

Specific Target Organ Toxicity - Single Exposure

 

Category 3

 

(Respiratory)

 

 

 

 

 

Signal word

Danger

 

 

 

Hazard statements

H225

Highly flammable liquid and vapor.

 

H315

Causes skin irritation.

Acrylic Primer#1602 LANG丙烯酸底漆 

H317 May cause an allergic skin reaction.

 

H335 May cause respiratory irritation.

Acrylic Primer / Jet Seal 041 v. 3 Page 1 of 8

Appearance Clear Physical state Liquid Odor Acrid

 

Precautionary Statements – Prevention

 

P210 Keep away from heat/sparks/open flames/ hot surfaces. No smoking.

 

P233 Keep container tightly closed.

 

P240 Ground/bond container and receiving equipment.

 

P241 Use explosion-proof electrical/ventilating/lighting/equipment.

 

P242 Use only non-sparking tools.

 

P243 Take precautionary measures against static discharge.

 

P261 Avoid breathing dust/fume/gas/mist/vapors/spray.

 

P264 Wash hands thoroughly after handling.

 

P271 Use only outdoors or in a well-ventilated area.

 

P272 Contaminated work clothing should not be allowed out of the workplace.

 

P280 Wear protective gloves/protective clothing/eye protection/face protection.

 

Precautionary Statements – Response

 

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediay all contaminated clothing. Rinse skin with water/shower.

 

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P312 Call a POISON CENTER or doctor/physician if you feel unwell.

 

P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P362 Take off contaminated clothing and wash before use.

 

P370+P378 In case of fire: Use CO2, for extinction.

 

Precautionary Statements – Storage

 

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P403+P235 Store in a well-ventilated place. Keep cool.

 

Precautionary Statements – Disposal

 

P501 Dispose of contents/container in accordance with local regulation.

 

Hazardous Component(s) Contains methyl methacrylate

for labeling

 

Hazards not otherwise classified (HNOC) Not applicable

 

Other Information Harmful to aquatic life

3. COMPOSITION / INFORMATION ON INGREDIENTS

 

Chemical Name

CAS No

Weight - %

Trade Secret

Methyl Methacrylate

80-62-6

<100

*

*Specific chemical weight has been

withheld as a trade secret.

 

 

 

 

4. FIRST AID MEASURES

First aid measures

 

Acrylic Primer / Jet Seal 041  v. 3

Page 2 of 8


 

 

ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Use personal protective equipment as required. Ensure adequate ventilation. Remove any contaminated clothing and wash thoroughly before reuse.

Inhalation

Remove victim to fresh air and keep at rest in a position comfortable for breathing. Keep patient warm and at

 

rest. Call a physician or poison control center immediay.

Eye contact

Immediay flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing

 

for at least 15 minutes. Call a physician immediay.

Ingestion

Do NOT induce vomiting. Drink plenty of water or milk immediay. Never give anything by mouth to an

 

unconscious person. Provide an estimate of the time at which the material was ingested and the amount of

 

the substance that was swallowed. Call a physician or poison control center immediay.

Skin Contact

Wash off immediay with plenty of soap and water. Take off contaminated clothing. Wash contaminated

 

clothing before reuse. If skin irritation or rash occurs, get medical advice/attention.

Most important symptoms and effects, both acute and delayed

Symptoms

May cause skin and eye irritation to the mucous membranes and upper respiratory tract.

Indication of any immediate medical attention and special treatment needed

Note to physicians

Treat symptoms conventionally, after thorough decontamination.

 

 

 

5. FIRE-FIGHTING MEASURES

 

Extinguishing Media

 

Suitable: Chemical foam, carbon dioxide (CO2), dry chemical

 

Unsuitable: Water spray

 

Specific hazards arising from the chemical

 

For bulk size >1L – High temperatures, inhibitor depletion, accidental impurities, or exposure to radiation or oxidizers may cause spontaneous polymerizing reaction generating heat/pressure. Closed containers may rupture or explode during a runaway polymerization. Use a water spray or fog to reduce or direct vapors. Extremely flammable. Vapors are heavier than air and may spread along the floors. Vapors may travel to source of ignition and flash back. Heat/impurities may cause pressure to build and/or rupture closed containers, spreading fire, increasing risk or burns/injuries.

 

Hazardous Combustion Products: Carbon oxides

 

Sensitivity to Mechanical Impact: No

 

Sensitivity to Static Discharge: Yes

 

Protective equipment and precautions for firefighters

 

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Fight fire from a safe location.

6. ACCIDENTAL RELEASE MEASURES

 

Personal precautions, protective equipment and emergency procedures

 

Personal precautions

 

 

 

Environmental precautions Prevent product from entering drains. Spillages or uncontrolled discharges into watercourses must

 

be alerted to the appropriate regulatory body.

 

Methods and material for containment and clean-up

 

Method for containment Absorb with earth, sand or other non-combustible material and transfer to containers for later

 

disposal. DO NOT use combustible materials such as sawdust.

 

Method for clean-up Use only non-sparking tools. Wash all affected areas with plenty of warm water and soap.

 

Acrylic Primer / Jet Seal 041 v. 3 Page 3 of 8


 

If anticipated that prolonged and repeated skin contact will occur during use of this product, wear gloves for routine industrial use. If necessary, refer to US OSHA 29CFR SS1910.138 or the appropriate standards of Canada or the EC member states. Wear suitable protective clothing.

 

Depending on the use of this product, safety glasses or goggles may be worn. If necessary, refer to US OSHA 29CFR SS1910.133, Canadian standards or the European Standard EN 166. Ensure that an eyewash station, sink or washbasin is available in case of exposure to eyes.

 

Keep in original container.

Strong oxidizing agents, strong reducing agents, free-radical generators, inert gases, oxygen scavengers

Material has strong solvent properties and can soften paint and rubber.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Consideration should be given to the work procedures involved and the potential extent of exposure as they may determine whether a higher level of protection is required. The following information is given as general guidance.

 

Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat, sparks, flame and other sources of ignition (i.e. pilot lights, electric motors and static electricity). Protect from direct sunlight. Keep container closed to prevent water absorption and contamination. Methacrylate stored in bulk must be kept in contact with air (oxygen). Keep at a temperature not exceeding 25°C.

7. HANDLING AND STORAGE

 

Precautions for safe handling

 

Advice on safe handling Observe precautions found on the label. Keep containers closed when not in use. All equipment used when handling the product must be grounded. Use non-sparking hand tools and explosion-proof electrical equipment. Avoid contact with skin and eyes. Avoid breathing vapors or mists. Use only in well-ventilated areas. Vapors are heavier than air and may travel along the floor and in the bottom of containers. Take precautionary measures against static discharges. Wash thoroughly after handling. Use personal protection recommended in Section 8. Contaminated work clothing should not be allowed out of the workplace. Keep away from heat, sparks, open flames, and hot surfaces. NO SMOKING.

 

Conditions for safe storage, including any incompatibilities

 

Storage Conditions

Packaging materials

Incompatible materials

Exposure guidelines

 

Chemical Name

ACGIH TLV

OSHA PEL

NIOSH IDLH

Methyl Methacrylate

S 100 ppm

TWA:100 ppm

IDLH: 1,000 ppm

80-62-6

TWA: 50 ppm

TWA: 410 mg/m3

TWA: 100 ppm

 

 

 

TWA: 410 mg/m3

Appropriate engineering controls

Engineering controls Apply technical measures to comply with the occupational exposure limits. Eyewash stations

Individual protection measures, such as personal protective equipment

Eye / face protection

Skin and body protection

Acrylic Primer / Jet Seal 041 v. 3 Page 4 of 8


 

Respiratory protection

Wear suitable respiratory equipment if exposure to levels above the occupational exposure limit is

 

 

likely. A suitable mask with filter type A may be appropriate. In the event of formation of particularly

 

 

high levels of vapor, a self-contained breathing apparatus may be appropriate.

General hygiene considerations

Handle in accordance with good industrial hygiene and safety practice.

 

 

 

 

 

 

9. PHYSICAL AND CHEMICAL PROPERTIES

 

 

 

 

Information on basic physical and chemical properties

 

 

Physical state

 

Liquid

Odor

Acrid

Appearance

 

Liquid

Odor threshold

Not determined

Color

 

Clear

 

 

Property

 

Values

Remarks / Method

 

pH

 

Not determined

 

 

Melting point /

freezing point

Not determined

 

 

Boiling point / boiling range

101°C / 214° F

 

 

Flash point

 

11.5°C / 52.7°F

 

 

Evaporation rate

3.1

Butyl acetate = 1

 

Flammability (solid, gas)

n/a (liquid)

 

 

Flammability limits in air

 

 

 

Upper flammability limit

12.5%

 

 

Lower flammability limit

2.12%

 

 

Vapor pressure

 

28mm Hg

@ 20°C

 

Vapor density

 

3.5

@15.5°C (Air = 1)

 

Specific gravity

 

0.891

Water = 1

 

Water solubility

 

1.6 wt%

 

 

Solubility in other solvents

Not determined

 

 

Partition coefficient

Not determined

 

 

Autoignition temperature

421°C / 790°F

 

 

Decomposition temperature

Not determined

 

 

Kinematic viscosity

Not determined

 

 

Dynamic viscosity

Not determined

 

 

Explosive properties

Not determined

 

 

Oxidizing properties

Not determined

 

 

Other information

 

 

 

Density

 

0.891 g/mL

 

 

 

 

 

 

 

 

10. STABILITY AND REACTIVITY

 

 

 

 

 

Reactivity

Not reactive under normal conditions

 

 

 

Chemical stability Unstable / reactive upon depletion of inhibitor

 

Possibility of hazardous reactions

 

None under normal processing

 

Hazardous polymerization Hazardous polymerization may occur. Monomer vapors are inhibited and may form polymers in vent or flame arresters, resulting in blockage of vents.

 

Conditions to avoid

 

Temperatures above 25°C (77°F), localized heat sources (e.g. drum or band heaters), oxidizing conditions, freezing conditions, direct sunlight, ultraviolet radiation, inert gas blanketing

 

Incompatible materials

 

Strong oxidizing agents, strong reducing agents, free-radical generators, inert gases, oxygen scavengers

 

Material has strong solvent properties and can soften paint and rubber.

 

Hazardous decomposition products Carbon oxides

 

Acrylic Primer / Jet Seal 041 v. 3 Page 5 of 8


 

 

May cause allergic skin reaction.

Not classifiable as a human carcinogen

 

 

11. TOXICOLOGICAL INFORMATION

 

 

 

 

 

 

Information on likely routes of exposures

 

 

 

Product information

 

 

 

 

 

Inhalation

Avoid breathing vapors or mists.

 

 

 

Eye contact

Causes severe eye irritation.

 

 

 

Skin contact

Causes skin irritation.

 

 

 

Ingestion

Not expected to be toxic following ingestion of amount recommended for use.

 

Component information

 

 

 

 

 

 

 

 

 

 

 

Chemical Name

 

ORAL LD50

DERMAL LD50

 

INHALATION LC50

Methyl Methacrylate

 

7872 mg/kg (rat)

>5 g/kg (rabbit)

 

400 ppm (rat) 1 h

80-62-6

 

 

 

 

4632 ppm (rat) 4 h

 

 

 

 

 

Information on physical, chemical and toxicological effects

 

 

 

Symptoms

May cause skin and eye irritation. May cause irritation to the mucous membranes and upper respiratory tract.

 

Delayed and immediate effects as well as chronic effects from short and long-term exposure

 

Sensitization

 

Carcinogenicity

 

Chemical Name

ACGIH

IARC

NTP

OSHA

Methyl Methacrylate

-

Group 3

-

-

80-62-6

 

 

 

 

 

 

 

 

 

IARC (International Agency

for Research on Cancer)

Group 3 IARC components are “not classifiable as human carcinogens”

 

STOT – single exposure May cause respiratory irritation. May cause drowsiness or dizziness.

 

Numerical measures of toxicity  Product Not determined

 

The following values are calculated based on chapter 3.1 of the GHS document.

 

ATEmix (oral)

7874

mg/kg

ATEmix (dermal)

5005

mg/kg

ATEmix (inhalation-gas)

400

mg/kg

12. ECOLOGICAL INFORMATION

 

Ecotoxicity Harmful to aquatic life.

 

Chemical Name

Algae / aquatic plants

Fish

Toxicity to

Crustacea

 

 

 

microorganisms

 

Methyl

170: 96 h

125.5-190.7: 96 h Pimephales

-

69: 48 h Daphnia magna

Methacrylate

Psuedokirchneriella

promelas mg/L LC50 static;

 

mg/L EC50

80-62-6

subcapitata mg/L EC50

153.9-341.8: 96 h Lepomis macrochirus mg/L

 

 

 

 

LC50 static;

 

 

 

 

170-206: 96 h Lepomis macrochirus mg/L

 

 

 

 

LC50 flow -through;

 

 

 

 

243-275: 96 h Pimephales promelas mg/L

 

 

 

 

LC50 flow-through;

 

 

 

 

326.4-426.9 96 h Poecilia reticulata mg/L

 

 

 

 

LC50 static;

 

 

 

 

>79: 96 h Oncorhynchus mykiss mg/L LC50

 

 

 

 

flow-through;

 

 

 

 

>79: 96 h Oncorhynchus mykiss mg/L LC50

 

 

 

 

static

 

 

Acrylic Primer / Jet Seal 041  v. 3

 

 

Page 6 of 8


 

 

 

Persistence and degradability Not readily biodegradable

 

 

 

 

 

 

 

Bioaccumulation

Not determined

 

 

 

 

 

 

 

Mobility

Potential for mobility in soil is very high.

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Chemical Name

 

 

 

Partition coefficient

 

 

 

 

 

 

Methyl Methacrylate

 

 

 

0.7

 

 

 

 

 

 

 

80-62-6

 

 

 

 

 

 

 

 

 

 

 

 

 

Other adverse effects

COD = 88% (28 days), DOC removal > 95% (28 days)

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

13. DISPOSAL CONSIDERATIONS

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Waste treatment methods

 

 

 

 

 

 

 

 

 

 

 

 

 

Disposal of wastes

 

Follow all local and national government regulations in disposing material or contaminated

 

 

 

 

 

 

packaging.

 

 

 

 

 

 

 

 

 

 

 

For U.S. - Dispose of in accordance with federal, state and local regulations. When discarded, it is

 

 

 

 

 

 

considered a hazardous waste by the EPA under RCRA. The reportable quantity for methyl

 

 

 

 

 

 

methacrylate is 1000 lb. (40 CFR Part 302). Add excess inhibitor before disposing.

 

 

Contaminated Packaging

 

Reuse of empty drums or containers is not recommended. Employees should be advised of the

 

 

 

 

 

 

potential hazards due to residual material associated with empty containers. Dispose of all empty

 

 

 

 

 

 

containers properly in accordance with federal, state and local regulations.

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Chemical Name

 

RCRA

 

RCRA – Basis for Listing

RCRA – D Series Wastes

 

RCRA – U Series Wastes

 

 

Methyl Methacrylate

 

U162

 

 

Included in waste stream;

-

 

 

 

U162

 

 

80-62-6

 

 

 

 

 

F039

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Chemical Name

 

 

California Hazardous Waste Status

 

 

 

 

 

Methyl Methacrylate

 

 

 

Toxic Ignitable

 

 

 

 

 

 

 

80-62-6

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

14. TRANSPORTATION INFORMATION

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

DOT

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

UN / ID No

 

 

 

 

 

UN1247

 

 

 

 

 

 

 

 

Proper shipping name

 

 

 

 

 

Methyl Methacrylate monomer, stabilized

 

 

 

 

Hazard Class

 

 

 

 

 

3

 

 

 

 

 

 

 

 

Packing Group

 

 

 

 

 

II

 

 

 

 

 

 

 

 

Reportable Quantity (RQ)

 

 

 

 

 

1000 lb.

 

 

 

 

 

 

 

IATA

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

UN / ID No

 

 

 

 

 

UN1247

 

 

 

 

 

 

 

 

Proper shipping name

 

 

 

 

 

Methyl Methacrylate monomer, stabilized

 

 

 

 

Hazard Class

 

 

 

 

 

3

 

 

 

 

 

 

 

 

Packing Group

 

 

 

 

 

II

 

 

 

 

 

 

 

IMDG

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

UN / ID No

 

 

 

 

 

UN1247

 

 

 

 

 

 

 

 

Proper shipping name

 

 

 

 

 

Methyl Methacrylate monomer, stabilized

 

 

 

 

Hazard Class

 

 

 

 

 

3

 

 

 

 

 

 

 

 

Packing Group

 

 

 

 

 

II

 

 

 

 

 

Acrylic Primer / Jet Seal 041 v. 3 Page 7 of 8

 

 

 

 

15. REGULATORY INFORMATION

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

International Inventories

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

TSCA

Listed

 

United States Toxic Substances Control Act, Section 8(b) Inventory

 

 

 

DSL

Listed

 

Canadian Domestic Substances List

 

 

 

 

 

 

 

EINECS

Listed

 

European Inventory of Existing Chemical Substances

 

 

 

EU Regulations

EC No. 1272/2008 (CLP) Classification, Labeling, Packaging

 

 

 

 

 

 

 

 

Medical Devices Directive 93/42/EEC - Class I Medical Devices

 

 

 

 

 

 

 

US Federal Regulations

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Chemical Name

 

CAS

 

 

 

Weight %

 

SARA 313 Threshold Values %

 

 

Methyl Methacrylate

 

80-62-6

 

 

 

< 100

 

 

1.0

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

SARA 311 / 312 Hazard Categories

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Chemical Name

 

 

CWA – Reportable

 

 

CWA – Toxic

 

 

CWA – Priority

 

CWA – Hazardous

 

 

 

 

 

Quantities

 

 

Pollutants

 

 

Pollutants

 

Substances

 

Methyl Methacrylate

 

 

1,000 lb.

 

 

-

 

 

-

 

 

X

 

80-62-6

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Chemical Name

 

Hazardous Substances

 

CERCLA /

 

 

Reportable Quantity (RQ)

 

 

 

 

 

RQs

 

SARA RQ

 

 

Final

 

 

 

Methyl Methacrylate

 

1,000 lb.

 

-

 

 

 

1,000 lb. / 454 kg

 

 

 

80-62-6

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

US State Right-to-Know Regulations

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Chemical Name

 

 

 

CAS

 

 

New Jersey

 

Massachusetts

 

Pennsylvania

Methyl Methacrylate

80-62-6

 

 

 

 

X

 

X

 

 

X

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

16. OTHER INFORMATION

 

NFPA

Health Hazards

 

Flammability

Instability

 

 

2

 

3

2

 

HMIS

Health Hazards

 

Flammability

Physical Hazards

 

 

2

 

3

2

 

Issue Date

26-Sept-2014

 

 

 

 

Revision Date

14-July-2015

 

 

 

 

Revision Note

Section 2 – revise classification categories, revise some Hazard Statements and Precautionary Statements,,

 

add hazardous component for labeling info

 

 

Information to be updated in due course

Hazard pictograms listed in this SDS to be added to product label

 

Disclaimer

 

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release. It is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

 

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